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207

Pb

a

U

b

Pb

b

Th

b 206

Pbc

c 207

Pb

d

±2s

206

Pb

d

±2s ȡ

e

207

Pb

d

±2s

206

Pb

f

±2s

207

Pb

f

±2s

207

Pb

f

±2s Conc.

g

(cps) (ppm) (ppm)

U (%)

235

U (%)

238

U (%) (rho)

206

Pb (%)

238

U (Ma)

235

U (Ma)

206

Pb (Ma) (%)

Grain

Felix

h

12482 435 68 2.47 0.2 0.6484 3.0 0.08211 3.0 0.43 0.05728 3.0 509 15 507 12 502 65 102

Plesovice

h

2852 651 34 0.09 1.3 0.3989 4.1 0.05419 2.2 0.48 0.05339 2.9 340 7 341 12 345 64 99

206

Pb/

238

U error is the quadratic additions of the within run precision (2 SE) and the external reproducibility (2 SD) of the reference zircon.

207

Pb/

206

Pb error propagation

(

207

Pb signal dependent) following Gerdes & Zeh (2009).

207

Pb/

235

U error is the quadratic addition of the

207

Pb/

206

Pb and

206

Pb/

238

U uncertainty.

a

Within run background-correctedmean

207

Pb signal in cps (counts per second).

b

U and Pb content and Th/U ratio were calculated relative to GJ-1 reference zircon.

c

Percentage of the common Pb on the

206

Pb. b.d. = below detection limit.

d

Pb/U and Pb/Pb ratios. Corrected for background, within-run Pb/U fractionation (in case of

206

Pb/

238

U) and common Pb using Stacy and Kramers (1975) model Pb

composition and subsequently normalised to GJ-1 (ID-TIMS value/measured value);

207

Pb/

235

U calculated using ((

207

Pb/

206

Pb)*(

238

U/

206

Pb)*137.88).

e

ZŚŽ ;ʌͿ ŝƐ ƚŚĞ ;

206

Pb/

238

U)/(

207

Pb/

235

U) error correlation coefficient.

f

Pb/U and Pb/Pb ages.

g

Degree of concordance = ((

206

Pb/

238

U age)/(

207

Pb/

206

Pb age)) x 100.

h

Mean of 13 (91500), 13 (Felix), 13 (Plesovice), and 23 (GJ-1) analyses, respectively.

230