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176

Yb

a

176

Lu

a

178

Hf

180

Hf Sig

Hf

b 176

Hf

176

Hf

d

“ ı

c

T

DM

e

age

f

177

Hf

177

Hf

177

Hf

177

Hf

(V)

177

Hf

177

Hf

(t)

İ+I (Ga) (Ma)

İ+I

(t)

d

Grain

“ ı

“ ı

±2ı

c

Plesovice_40-5-90_3

0

.0060 5 0.00015 1 1

.46725 1.88682 14 0.282463 28 0.282462 -3.9 1.0 1.24 338

Plesovice_40-5-90_4

0.0035 3 0.00008 0 1.46713 1.88687 14 0.282466 24 0.282465 -3.8 0.9 1.23 338

Plesovice_40-5-90_5

0.0025 2 0.00006 0 1.46723 1.88694 14 0.282480 25 0.282480 -3.3 0.9 1.20 338

Plesovice_40-5-90_6

0

.0057 5 0.00013 1 1

.46727 1.88698 13 0.282515 29 0.282514 -2.1 1.0 1.14 338

Plesovice_40-5-90_7

0.0038 3 0.00009 1 1.46717 1.88670 13 0.282442 22 0.282441 -4.6 0.8 1.28 338

06-Nov

Plesovice_40-5-90_1

0

.0055 4 0.00012 1 1

.46719 1.88672 13 0.282471 23 0.282470 -3.6 0.8 1.22 338

Plesovice_40-5-90_2

0.0035 3 0.00008 0 1.46718 1.88697 11 0.282463 34 0.282462 -3.9 1.2 1.24 338

Plesovice_40-5-90_3

0

.0079 6 0.00017 1

1.46718 1.88674 14 0.282446 20 0.282445 -4.5 0.7 1.27 338

Plesovice_40-5-90_4

0.0126 10 0.00029 2 1.46719 1.88684 12 0.282460 27 0.282458 -4.1 0.9 1.25 338

Plesovice_40-5-90_5

0

.0056 5 0.00013 1 1

.46724 1.88698 13 0.282482 32 0.282481 -3.2 1.1 1.20 338

Plesovice_40-5-90_6

0

.0047 4 0.00011 1 1

.46721 1.88689 13 0.282477 28 0.282477 -3.4 1.0 1.21 338

Plesovice_40-5-90_7

0.0025 2 0.00006 0 1.46716 1.88683 15 0.282448 46 0.282448 -4.4 1.6 1.27 338

Plesovice_40-5-90_7bis

0

.0063 5 0.00014 1 1

.46724 1.88692 13 0.282481 23 0.282480 -3.3 0.8 1.20 338

Plesovice_40-5-90_8

0

.0052 4 0.00012 1 1

.46721 1.88677 13 0.282478 22 0.282478 -3.4 0.8 1.21 338

Plesovice_40-5-90_9

0

.0049 4 0.00011 1 1

.46721 1.88679 13 0.282490 27 0.282489 -2.9 1.0 1.19 338

Plesovice_40-5-90_10

0

.0031 3 0.00007 0 1

.46716 1.88673 14 0.282472 24 0.282472 -3.5 0.8 1.22 338

Plesovice_40-5-90_11

0

.0079 6 0.00018 1

1.46721 1.88693 13 0.282497 26 0.282496 -2.7 0.9 1.17 338

07-Nov

Plesovice-100-100-5_1

0

.0034 3 0.00008 0 1

.46717 1.88671 15 0.282465 22 0.282465 -3.8 0.8 1.23 338

Plesovice-100-90-5_2

0

.0049 4 0.00012 1 1

.46719 1.88685 14 0.282469 17 0.282468 -3.7 0.6 1.23 338

Plesovice-100-90-5_3

0

.0036 3 0.00008 1 1

.46716 1.88672 13 0.282468 22 0.282467 -3.7 0.8 1.23 338

Plesovice-100-90-5_4

0

.0039 3 0.00009 1 1

.46720 1.88670 15 0.282455 20 0.282454 -4.2 0.7 1.25 338

Plesovice-100-90-5_5

0

.0051 4 0.00012 1 1

.46724 1.88685 13 0.282481 26 0.282480 -3.3 0.9 1.20 338

Plesovice-100-90-5_6

0

.0055 4 0.00013 1 1

.46717 1.88679 13 0.282459 23 0.282458 -4.0 0.8 1.25 338

Plesovice-100-90-5_7

0

.0053 4 0.00013 1 1

.46724 1.88680 13 0.282493 20 0.282493 -2.8 0.7 1.18 338

Plesovice-100-90-5_8

0.0059 5 0.

00014 1 1.46717 1

.88676 14 0.282456 25 0.282455 -4.1 0.9 1.25 338

Mean

0

.0054 37 0.00012 8

1.46719 1.88677 14 0.282466 31 0.282466 -3.8 1.1 1.23

41

Quoted uncertainties (absolute) relate to the last quoted figure. The effect of the inter-element fractionation on Lu/Hf was estimated to be

about 6 % or less based on analyses of the GJ-1 and WůĞƐŽǀŝēĞ zircon. Accuracy and reproducibility was checked by repeated analyses of

reference zircon GJ-1 and WůĞƐŽǀŝēĞ (data given as mean with 2 standard deviation uncertainties).

(a)

176

Yb/

177

Hf = (

176

Yb/

173

Yb)

true

x (

173

Yb/

177

Hf)

meas

x (M

173(Yb)

/M

177(Hf)

)

ɴ;,ĨͿ

, ɴ;,ĨͿ = ln((

179

Hf/

177

Hf

true

)/(

179

Hf/

177

Hf

measured

)) / ln(M

179(Hf)

/M

177(Hf)

), M

= mass of respective isotopes. The

176

Lu/

177

Hf was calculated in a similar way using

175

Lu/

177

Hf and ɴ;zďͿ.

(b)

Mean Hf signal in volts.

(c)

Uncertainties are quadratic additions of the within-run precision and the daily reproducibility of the 40ppb-JMC475 solution. Uncertainties

for the JMC475 quoted at 2SD (2 standard deviation).

(d)

Initial

176

Hf/

177

Hf and ɸ,Ĩ calculated using the apparent U-Pb age determined by LA-ICP-MS dating (see column f), and the CHUR

parameters:

176

Lu/

177

Hf = 0.0336, and

176

Hf/

177

Hf = 0.282785 (Bouvier et al. 2008).

(e)

Two stage model age in Ga using measured

176

Lu/

177

Lu of each spot (first stage = age of zircon), a value of 0.0113 for the average

continental crust (second stage, values compiled from Rudnick and Gao (2003), and depleted mantle

176

Lu/

177

Lu = 0.0379, and

176

Hf/

177

Hf =

0.283164.

(f)

Apparent U-Pb age determined by LA-ICP-MS.

288