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176

Yb

a

176

Lu

a

178

Hf

180

Hf Sig

Hf

b 176

Hf

176

Hf

d

“ ı

c

T

DM

e

age

f

“ ı U-Pb

g

Lu-Hf

h

177

Hf

177

Hf

177

Hf

177

Hf

(V)

177

Hf

177

Hf

(t)

İ+I (Ga) (Ma) (Ma) conc seq

İ+I

(t)

d

Grain

“ ı

“ ı

±2ı

c

Quoted uncertainties (absolute) relate to the last quoted figure. The effect of the inter-element fractionation on Lu/Hf was estimated to be about 6 % or

less based on analyses of the GJ-ϭ ĂŶĚ WůĞƐŽǀŝēĞ njŝƌĐŽŶ͘ ĐĐƵƌĂĐLJ ĂŶĚ ƌĞƉƌŽĚƵĐŝďŝůŝƚLJ ǁĂƐ ĐŚĞĐŬĞĚ ďLJ ƌĞƉĞĂƚĞĚ ĂŶĂůLJƐĞƐ ŽĨ ƌĞĨĞƌĞnce zircon GJ-1 and

WůĞƐŽǀŝēĞ ;ĚĂƚĂ ŐŝǀĞŶ ĂƐ ŵĞĂŶ ǁŝƚŚ Ϯ ƐƚĂŶĚĂƌĚ ĚĞǀŝĂƚŝŽŶ ƵŶĐĞƌƚĂŝŶƚŝĞƐͿ͘

(a)

176

Yb/

177

Hf = (

176

Yb/

173

Yb)

true

x (

173

Yb/

177

Hf)

meas

x (M

173(Yb)

/M

177(Hf)

)

ɴ;,ĨͿ

͕ ɴ;,ĨͿ с ůŶ;;

179

Hf/

177

Hf

true

)/(

179

Hf/

177

Hf

measured

)) / ln(M

179(Hf)

/M

177(Hf)

), M = mass of

respective isotopes. The

176

Lu/

177

Hf was calculated in a similar way using

175

Lu/

177

,Ĩ ĂŶĚ ɴ;zďͿ͘

(b)

Mean Hf signal in volts.

(c)

Uncertainties are quadratic additions of the within-run precision and the daily reproducibility of the 40ppb-JMC475 solution. Uncertainties for the

JMC475 quoted at 2SD (2 standard deviation).

(d)

Initial

176

Hf/

177

,Ĩ ĂŶĚ ɸ,Ĩ ĐĂůĐƵůĂƚĞĚ ƵƐŝŶŐ ƚŚĞ ĂƉƉĂƌĞŶƚ h-Pb age determined by LA-ICP-MSdating (see column f), and the CHUR parameters:

176

Lu/

177

Hf =

0.0336, and

176

Hf/

177

Hf = 0.282785 (Bouvier et al. 2008).

(e)

Two stage model age in Ga using measured

176

Lu/

177

Lu of each spot (first stage = age of zircon), a value of 0.0113 for the average continental crust

(second stage, values compiled from Rudnick and Gao (2003), and depleted mantle

176

Lu/

177

Lu = 0.0379, and

176

Hf/

177

Hf = 0.283164.

(f)

Apparent U-Pb age determined by LA-ICP-MS.

(g)

U-Pb age concordance (%).

(h)

Sequence in which Lu-Hf analyses were performed. Standard analyses for each sequence are showed on Table 12.

323