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197

gabbroic or basaltic protolith from 505 to 485 Ma

(zircon crystallisation climax at

c

. 485 Ma).

From the second sample studied (GCH-20,

section 7.3.2) it was concluded that the protolith

mafic rock was crystallised almost directly from

a DM source, and that a HP–HT metamorphic

event induced extreme zircon solid-state

recrystallisation of the protolith zircon between

372 and 410 Ma, with a zircon crystallisation

climax at 390 Ma.

From the third sample studied (GCH-22,

section 7.3.3) it was concluded that the age

of crystallisation of the protolith material is

constrained between 482 and 473 Ma, with a

zircon crystallisation climax at 473 Ma. This

protolithic zircon overgrew at high-T conditions

at

c

. 395 Ma together with, or subsequent to,

metamorphic Grt.

From the fourth sample studied (GCH-

23, section 7.3.4) it was concluded that the

protolithic zircon crystallised at around

c

. 508

Ma. This mafic rock was intruded by a felsic rock

(GCH-14, section 7.4.4) at

c

. 500 Ma, inducing a

high-T input in the mafic rock, which triggered

zircon pseudomorphic alteration at

c

. 489 Ma,

with no presence of a fluid phase.

The four eclogites have been represented

together in Fig. 93, which combines the

H

Hf

(t)

data of the four samples and the U–Pb combined

density diagram of these four and of the detrital

zircon of the HP–HT metasedimentary rocks

(Banded Gneisses). This combined figure shows

a zircon crystallisation climax for the Cambrian–

Ordovician eclogite population at

c

. 480 Ma and

a relative abundance peak at

c

. 505 Ma. Both ages

are interpreted as the ages of the protolith mafic

generation, but the possibility of a generation

at

c

. 505 Ma and a metamorphic event at

c

. 480

Ma cannot be discarded or proved. The sources

of the mafic protolith rocks are varied. Two

samples (GCH-19 and GCH-20) show that their

protoliths are almost directly derived from a

depleted mantle source, most probably by direct

partial fusion of it. The geological environment

in which these primitive and juvenile protolithic

rocks are enclosed is a back-arc type basin where

the oceanic crust is generated as the basin widens

and evolves. This environment fits perfectly

with a juvenile source protolith origin for these

eclogites. The other two samples (GCH-22

and GCH-23) have

H

Hf

(t)

and

H

Nd

(t)

values not

compatible with a juvenile source derivation

for the genesis of their protoliths. It seems that

the only possible ways to explain a non-juvenile

derivation of a basic rock are: (i) as a partial

fusion of an enriched mantle component, or (ii)

as an important contamination of a depleted

mantle partial melt with continental crust

material. Both explanations are probable, since

in a magmatic arc system, contamination is

very possible due to the intrusion of juvenile

materials into continental crust ones, the same

way as an enriched mantle component is also

very probably present in this geological context.

This enriched component could be, for example,

the subcontinental mantle of Gondwana, which

evolved separately from the depleted mantle

since the Mesoproterozoic (Nd model ages and

the average of Hf zircon model ages fall in the

Mesoproterozoic Era).

The zircon crystallisation climax is

c

. 393 Ma

for the Devonian eclogite population. This age

is interpreted to be the age of maximum zircon

crystallisation due to a HP–HT metamorphic

event. This metamorphism triggered solid-

state recrystallisation of inherited zircon and

also zircon overgrowths at high temperature

conditions, most probably near the metamorphic

path temperature peak.

7.5.3. Orthogneisses

From the first sample studied (GCH-01,

section 7.4.1) it was concluded that the magmatic

protolith zircon crystallised between 518 and

466 Ma with a crystallisation climax at

c

. 496 Ma.

A solid-state recrystallisation of the protolithic

zircon triggered by a high-grade metamorphic

event took place between 410 and 381 Ma, with a

crystallisation climax at

c

. 402 Ma.

From the second sample studied (GCH-

03, section 7.4.2) it was concluded that the

protolithic zircon crystallised between 510 and

450 Ma, with a crystallisation climax at

c

. 485

Ma, and that a posterior recrystallisation event

altered the zircon textures without triggering any

rare element purge from the zircon structures.

7.5. DISCUSSION