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140

conserve their original

176

Hf/

177

Hf

(t)

ratios. Some

of the zircon textures favour this interpretation

for domain II zircon from this sample. Some

of the domain II zircon rims show badly

defined oscillatory textures (

e.g.

A056; Fig. 12)

and domain I zircon cores are surrounded by

alteration fronts (Fig. 12). In some cases domain

I cores show patchy chaotic textures, which are

interpreted as an extreme development of the

alteration fronts (

e.g.

A056, A020, A015; Fig. 12).

The process responsible for the development of

these textures is the exsolution of enriched REE

zircon into depleted REE zircon and xenotime

(with the addition of U–Th-silicates as a product,

Tomaschek

et al.

, 2003), following the reaction

(Zr,Hf,Y,REE)(Si,P)O

4

→ (Zr,Hf)SiO

4

+ (Y,REE)

PO

4

(Pan, 1997). This process is a consequence

of REE purge from the zircon structure triggered

by solid-state recrystallisation. Moreover, the

chaotic patchy cores are normally surrounded

by cracks (BSE images; Fig. 12) that could well

be the result of volume change in these cores

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Fig. 12.

BSE and CL images of representative zircons from the studied sample. Images without circles are BSE (back-scattered

electrons) images, and those with circles are CL (cathodoluminescence) images. Laser ablation pits for U–Pb analyses (red

line circles) have 30

μ

m diameters. Laser ablation pits for Lu–Hf analyses (green line circles) have 33

μ

m diameters. White

numbers are the reference number of the analysis, red numbers are the U–Pb age and its 2

σ

error (Ma) and the green

numbers are the

H

Hf values for the U–Pb age.

7.2. LEUCOSOMES