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139

zircon plot around 0.282679 ± 0.000037 (±2 SD;

Fig. 13b), and

176

Hf/

177

Hf

(t)

ratios for domain I

zircon plot at 0.282609 ± 0.000214 (±2 SD; Fig.

13b). If the two lower ratios are not considered,

domain I ratios are in the range of 0.282650 ±

0.000036 (±2 SD; Fig. 13b).

Domain II Th/U ratios are always below

0.2, and vary from

c.

0.004 to

c.

0.033 (average:

0.011); and domain I Th/U ratios are higher

(higher than 0.2) and more variable, from

c.

0.40

to

c.

0.92 (average: 0.58; Fig. 14a). U content of

domain II analysed zircon is highly variable, in

the range of 20–2074 ppm (average: 223 ppm). U

content of domain I analysed zircon is variable,

but not as much as domain II, in the range of

76–885 ppm (average: 403 ppm; Appx. 4).

176

Lu/

177

Hf ratios of domain II zircon are low

and vary from

c.

0.00013 to

c.

0.00066 (average:

0.00035; Fig. 14b).

176

Lu/

177

Hf ratios of domain

I zircon are higher than those of domain II and

vary from

c.

0.00080 to

c.

0.00230 (average:

0.00154; Fig. 14b).

176

Yb/

177

Hf ratios of domain

II zircon are low and vary from

c.

0.0028 to

c.

0.0206 (average: 0.0098; Appx. 4).

176

Yb/

177

Hf

ratios of domain I zircon are higher than those

of domain II and vary from

c.

0.0217 to

c.

0.0657

(average: 0.0447; Appx. 4).

Nd whole-rock model-age is 0.92 Ga and

H

Nd

(t)

values are:

H

Nd

(t=0)

= -1.6;

H

Nd

(t=389)

= +1.6.

7.2.2.2. Discussion

U–Pb ages can be sub-divided into three

groups, the old inheritances, Cambrian–

Ordovician domain I zircon and Devonian

domain II zircon. The younger population in this

sample, domain II, has similar

176

Hf/

177

Hf

(t)

ratios

within error than domain I zircon (Fig. 13b).

These observations suggest that domain II zircon

is a consequence of solid-state recrystallisation

of domain I zircon. As explained in the previous

sample (leucosome GCH-25), zircon domains

altered by pseudomorphic recrystallisation

Fig. 10.

U-Pb conventional concordia diagram showing

U-Pb zircon analyses of the studied sample. Ellipses repre-

sent combined 2

σ

uncertainties of

206

Pb/

238

U and

207

Pb/

235

U

ratios.

n

, number of analyses considered (those with 90–

110% concordance)/total number of U–Pb analyses.

3E 8

GDWD SRLQW HUURU HOLSVHV DUH ı

3E 8

*&+

/HXFRVRPH

Q

Fig. 11.

Adaptative Kernel Density Estimation (aKDE, continuous line enclosing the blue area), Probability Density (PDP,

black dashed line) and histogram diagrams of the U–Pb analyses (calculated with DensityPlotter5.0, Vermeesch 2012).

Numbers in the vertical axis represent histogram frequency;

n

, number of analyses.

a

Partial plot representing data within

a 300–700 Ma time range (bandwidth = 5 Ma, binwidth = 5 Ma).

b

Complete plot (bandwidth = 15 Ma, binwidth = 25 Ma).

3DOHRSURWHUR]RLF

0HVR

SURWHUR]RLF

3DOHR]RLF DQG

1HRSURWHUR]RLF

$UFKHDQ

>0D@

Q

Q

D

E

7.2. LEUCOSOMES