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144

badly defined or even structure-less. The domain

II rims are the outer features observed and define

the crystals outer habit, which normally show

well defined crystal faces and the long crystal

axis to be between two and four times longer

than the short axis (Fig. 19).

Domain II

H

Hf

(t)

values are between

c.

-3.5 and

+3.1 (average: +0.8; Fig. 20a). Domain I

H

Hf

(t)

values are between

c.

-8.8 and +3.9 (average: 0.0;

Fig. 20a).

176

Hf/

177

Hf

(t)

ratios for domain II zircon

plot around 0.282559 ± 0.000098 (±2 SD; Fig.

20b), and

176

Hf/

177

Hf

(t)

ratios for domain I zircon

plot at 0.282473 ± 0.000233 (±2 SD; Fig. 20b).

U content of domain II analysed zircon is

highly variable, in the range of 98–2783 ppm

(average: 585 ppm). U content of domain I

analysed zircon is also highly variable, in the

range of 45–1770 ppm (average: 397 ppm; Appx.

4). Domain II Th/U ratios are always below 0.2,

and vary from 0.002 to

c.

0.034 (average: 0.011),

and domain I Th/U ratios are higher and more

variable, from

c.

0.01 to

c.

1.09 (average: 0.42;

Fig. 21a).

176

Lu/

177

Hf ratios of domain II zircon are low

and vary from

c.

0.00002 to 0.00035 (average:

0.00007; Fig. 21b).

176

Lu/

177

Hf ratios of domain

I zircon are higher than those of domain II,

and vary from

c.

0.00057 to 0.00193 (average:

0.00118; Fig. 21b).

176

Yb/

177

Hf ratios of domain II

zircon are low and vary from

c.

0.0006 to 0.0139

(average: 0.0024; Appx. 4).

176

Yb/

177

Hf ratios of

domain I zircon are higher than those of domain

II, and vary from

c.

0.0162 to 0.0551 (average:

0.0349; Appx. 4).

Nd whole-rock model-age is 1.52 Ga and

H

Nd

(t)

values are:

H

Nd

(t=0)

= -2.9;

H

Nd

(t=394)

= -1.0.

7.2.3.2. Discussion

U–Pb ages can be sub-divided into three

groups, the old inheritances, Cambrian–

Ordovician domain I zircon and Devonian

domain II zircon. The younger population in this

Fig. 17.

U-Pb conventional concordia diagram showing

U-Pb zircon analyses of the studied sample. Ellipses repre-

sent combined 2

σ

uncertainties of

206

Pb/

238

U and

207

Pb/

235

U

ratios.

n

, number of analyses considered (those with 90–

110% concordance)/total number of U–Pb analyses.

3E 8

GDWD SRLQW HUURU HOLSVHV DUH ı

3E 8

*&+

/HXFRVRPH

Q

Fig. 18.

Adaptative Kernel Density Estimation (aKDE, continuous line enclosing the blue area), Probability Density (PDP,

black dashed line) and histogram diagrams of the U–Pb analyses (calculated with DensityPlotter5.0, Vermeesch 2012).

Numbers in the vertical axis represent histogram frequency;

n

, number of analyses.

a

Partial plot representing data within

a 300–700 Ma time range (bandwidth = 5 Ma, binwidth = 5 Ma).

b

Complete plot (bandwidth = 15 Ma, binwidth = 25 Ma).

3DOHRSURWHUR]RLF

0HVR

SURWHUR]RLF

3DOHR]RLF DQG

1HRSURWHUR]RLF

$UFKHDQ

>0D@

Q

Q

D

E

7.2. LEUCOSOMES