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179

maximum: 337; Appx. 4). The majority of the

zircon grains have Th/U ratios higher than 0.2,

with an average value of 0.82 (minimum: 0.18,

maximum: 1.51). Only one analysis has lower

Th/U values lower than 0.2 (Fig. 70a).

176

Lu/

177

Hf ratios plot around 0.00122 ±

0.00126

r

2 SD; Fig. 70b).

176

Yb/

177

Hf ratios plot

around 0.0389 ± 0.0409 (±2 SD; Appx. 4).

Nd whole-rock experiments failed to calculate

a model-age, because the

147

Sm/

144

Nd ratio

calculated for this sample has a negative slope

in the

H

Nd

(t)

v.

age plot (higher value than

CHURs

147

Sm/

144

Nd value of 0.1967; Jacobsen &

Wasserburg, 1980). Epsilon value for present day

is:

H

Nd

(t=0)

= -0.6.

7.4.3.2. Discussion

Zircon from this sample shows a high

variety of textures and chemical ratios and

values. It has not been possible to relate these

observations with certain age ranges. The

maximum abundance peak of 504 Ma (Fig. 67)

is interpreted as the age of igneous crystallisation

of the protolithic felsic magmas. The variety of

textures displayed (Fig. 68) points to a complex

evolution after crystallisation, and possibly to

complex crystallisation processes where a high

number of inherited zircon grains may have

played an important role. The high variability

in their

H

Hf

(t)

values is not compatible with a

direct crystallisation of the whole population of

zircon from an homogeneous fluid phase (Fig.

69a). The high and varied Th/U,

176

Lu/

177

Hf and

176

Yb/

177

Hf ratios constitute evidence that zircon

was not subjected to a rare element purge due to

solid-state recrystallisation processes (Fig. 70 &

Appx. 4). But a pseudomorphic recrystallisation

process seems probable and expected from

textural observations, as the oscillatory

patterns are normally blurred and faded (Fig.

68). Other textural observations such as the

alotriomorphic character of zircon habits, point

to a fragmentation of the zircon grains due to

Fig. 66.

U-Pb conventional concordia diagram showing

U-Pb zircon analyses of the studied sample. Ellipses repre-

sent combined 2

σ

uncertainties of

206

Pb/

238

U and

207

Pb/

235

U

ratios.

n

, number of analyses considered (those with 90–

110% concordance)/total number of U–Pb analyses.

3E 8

GDWD SRLQW HUURU HOLSVHV DUH ı

3E 8

*&+

2UWKRJQHLVV

Q

Fig. 67.

Adaptative Kernel Density Estimation (aKDE, continuous line enclosing the blue area), Probability Density (PDP,

black dashed line) and histogram diagrams of the U–Pb analyses (calculated with DensityPlotter5.0, Vermeesch 2012).

Numbers in the vertical axis represent histogram frequency;

n

, number of analyses.

a

Partial plot representing data within

a 300–700 Ma time range (bandwidth = 5 Ma, binwidth = 5 Ma).

b

Complete plot (bandwidth = 15 Ma, binwidth = 25 Ma).

3DOHRSURWHUR]RLF

0HVR

SURWHUR]RLF

3DOHR]RLF DQG

1HRSURWHUR]RLF

$UFKHDQ

>0D@

Q

Q

D

E

7.4. ORTHOGNEISSES