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154

7.3.2.1. Results

From this sample (GCH-20), 83U–Pb analyses

were performed of which 82 were concordant (

d

= 1.2%; Figs. 31 & 32). The majority of the U–Pb

ages are grouped between 372 and 410 Ma, with

a maximum abundance at 390 Ma (domain II;

Fig. 32a), and only three zircon grains (domain

I) are older than 420 Ma.

Zircon in this sample show highly blurred

and fainted dark oscillatory zonings. Most of

the textures are so blurred that they can be

considered structure-less. Some of the domain

II (390 Ma) zircon show overgrowths, that are

brighter in the CL images than their cores (they

were not analysed because they are too small,

c.

1

P

m; see Fig. 33). Other zircon grains from

this same group show structure-less inherited

cores (Fig. 33). When zircon of this sample was

hand-picked many apatites were selected. The

CL images of these apatites show that their REE

contents are extremely high, even higher than

zircon (their images are darker than the zircon

images). No internal features are observed in

BSE images.

Domain II

H

Hf

(t)

values are high and plot

around the MORB-DM evolution trend with

values between

c.

+7.7 and +12.1 (average: +10.1;

Fig. 34a). Domain I

H

Hf

(t)

values are also high

with values of +13.0, +13.1 and +14.2 (average:

+13.4; Fig. 34a).

176

Hf/

177

Hf

(t)

ratios for domain

II zircon plot around 0.282821 ± 0.000061 (±2

SD; Fig. 34b), and

176

Hf/

177

Hf

(t)

ratios for domain

I zircon plot at 0.282859 ± 0.000016 (±2 SD; Fig.

34b).

U content of domain II analysed zircon is

very low, 111–655 ppm (average: 409 ppm). U

content of domain I analysed zircon is lower than

domain II zircon, 6–27 ppm (average: 16 ppm).

Domain II Th/U ratios vary from

c.

0.0002 to

0.01. Domain I Th/U ratios are higher, from

c.

0.1 to

c.

0.8 (average: 0.25; Fig. 35a).

Fig. 31.

U-Pb conventional concordia diagram showing

U-Pb zircon analyses of the studied sample. Ellipses repre-

sent combined 2

σ

uncertainties of

206

Pb/

238

U and

207

Pb/

235

U

ratios.

n

, number of analyses considered (those with 90–

110% concordance)/total number of U–Pb analyses.

3E 8

GDWD SRLQW HUURU HOLSVHV DUH ı

3E 8

*&+

(FORJLWH

Q

Fig. 32.

Adaptative Kernel Density Estimation (aKDE, continuous line enclosing the blue area), Probability Density (PDP,

black dashed line) and histogram diagrams of the U–Pb analyses (calculated with DensityPlotter5.0, Vermeesch 2012).

Numbers in the vertical axis represent histogram frequency;

n

, number of analyses.

a

Partial plot representing data within

a 300–700 Ma time range (bandwidth = 5 Ma, binwidth = 5 Ma).

b

Complete plot (bandwidth = 15 Ma, binwidth = 25 Ma).

3DOHRSURWHUR]RLF

0HVR

SURWHUR]RLF

3DOHR]RLF DQG

1HRSURWHUR]RLF

$UFKHDQ

>0D@

Q

Q

D

E

7.3. ECLOGITES